Jan 27, 2016

The Center for Integrated Nanostructure Physics (CINAP) within IBS has reported results correlating the flake merging angle with grain boundary (GBs) properties, and proven that increasing the merging angle of GBs drastically improves the flow of electrons. This correlates to an increase in the carrier mobility from less than 1 cm²V^-1s^-1 for small angles, to 16cm2 V-1s-1 for angles greater than 20°. The paper, entitled, ‘Misorientation-angle-dependent electrical transport across molybdenum disulfide grain boundaries’ is published in the journal Nature Communication.

According to the paper, it is essential to understand the atomic structures of GBs in order to control and improve electrical transport properties in both bulk and low-dimensional materials. Grain boundaries are the direction that atoms are arranged in a material. For the experiments undertaken by scientists at CINAP, a monolayer molybdenum disulfide (MoS₂) was grown by chemical vapour deposition (CVD) and subsequently transferred to a substrate of silicon dioxide (SiO2). The team’s reasoning for using MoS₂ is twofold: firstly, it is a 2D semiconductor that features high electrical conductance and, crucially, has a natural bandgap, which enables it to be tuned on and off and; secondly, the grain boundaries are well-defined. This is paramount for successful experiments. Previous research from Northwestern University found that the GBs of MoS₂ provided a unique way to modulate resistance; this was achieved by using a large electric field to spatially modulate the location of the grain boundaries.

The Northwestern results, published last year in Nature Nanotechnology, opened a pathway for future research, but the debate regarding the transport physics at the GB is still under dispute. This is due to a large device-to-device performance variation, poor single-domain carrier mobility, and, most importantly, a lack of correlation between transport properties and GB atomic structures in MoS₂ research. The CINAP team, headed by the Center’s director Young Hee Lee, overcame these obstacles by directly correlating four-probe transport measurements across single GBs with both high-resolution transmission electron microscopy (TEM) imaging and first-principles calculations. TEM is a microscopy technique whereby a beam of electrons is transmitted through an ultra-thin specimen, interacting with the specimen as it passes through. An exact atomic-scale image is formed from the interaction of the electrons transmitted through the specimen.

Identifying Grain Boundaries

GBs in the MoS₂ layers were identified and regions with no sign of wrinkling or multilayers were then selected to prevent misinterpretations. Four-probe transport measurements were then performed on the substrate with surprising results; when measuring flake misorientations of 8–20o, mobility increased from much less than 1 cm²V^-1s^-1 up to 16cm2 V-1s-1. Above 20o field effect mobility saturates at a 16cm2 V-1s-1 intra-domain cutoff. Thus, GBs between flakes having a misorientation angle of 20–60o show better transport properties.

The team has, as reported in their paper, “provided a more unified picture of the relationship between mobility, merging angle and atomistic structures of the GBs of monolayer MoS₂.” The results provide practical expectations regarding transport properties in large-area films, which will be restricted largely by the poor mobility across GBs. The results obtained in this work are applicable to other similar 2D systems, and contribute to the fundamental understanding of transport in semiconductors.

▲ Observing the location and angle of the GBs and the atomic struct

▲ Abnormal electical resistance of the GBs of large-area MoS₂

Notes for editors

- References
Thuc Hue Ly1,*, David J. Perello1,*, Jiong Zhao1,*, Qingming Deng2, Hyun Kim1,3, Gang Hee Han1, Sang Hoon Chae1, Hye Yun Jeong1,3 & Young Hee Lee1,3; Misorientation-angle-dependent electrical transport across molybdenum disulfide grain boundaries ,DOI: 10.1038/ncomms10426

- Media Contact
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- About the Institute for Basic Science (IBS)
IBS was founded in 2011 by the government of the Republic of Korea with the sole purpose of driving forward the development of basic science in Korea It comprises a total of 50 research centers in all fields of basic science, including mathematics, physics, chemistry, life science, earth science and interdisciplinary science. IBS has launched 26 research centers as of January 2016. There are 8 physics, 1 mathematics, 6 chemistry, 8 life science, and 3 interdisciplinary research centers.